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Research

Research at the Spanopoulos Group focuses on utilizing molecular and crystal engineering for the design and synthesis of next generation, environmentally stable and friendly hybrid materials. These materials feature multiple functionalities, targeting applications such as photovoltaics, spintronics, sensing, gas storage, gas separation, environmental remediation and photo-catalysis. The hybrid nature of the corresponding compounds is advantageous, combining both the merits of organic (e.g. tunable functionalization and mechanical properties) and  inorganic constituents (e.g. semiconduction/magnetism) for the creation of novel structural and functional motifs.

Research Areas

Porous Metal Halide Semiconductors (PMHS)

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1. A. Azmy, et al., Angew. Chem. Int. Ed. 2023, 62, e202218429  (Inside Cover + Team Profile)

2. A. Azmy, et al., ACS Appl. Mater. Interfaces 2023, 15, 42717

     The generation of porosity to fully inorganic semiconductors enhanced their optoelectronic features and rendered them proper for uncharted applications, such as photocatalysis and energy storage.

    Motivated by these attributes, we utilized molecular and crystal engineering to generate porosity to hybrid metal halide semiconductors (MHS) by using molecular cages serving as both structure-directing agents and counter-cations. Their presence not only rendered corresponding materials porous but also water-stable. Our work set the foundation for the development of a new family of materials, namely Porous Metal Halide Semiconductors (PMHS), offering fully customizable porosity and optoelectronic properties.  

     The porous nature and record water stability allow them to be utilized in various applications such as photocatalysis, sensing, photonic crystals, integrated waveguides, and solid-state batteries, to name a few.

Multi-functional Antibacterial Materials

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1. A. Azmy, et al., ACS Appl. Mater. Interfaces 2023, 15, 42717.

   Antimicrobial Resistance (AMR) is identified by the World Health Organization (WHO) as one of the greatest threats humanity faces, and this problem is expected to deteriorate over the following decades. Next-generation antibacterial materials are greatly sought after since they offer multiple advantages compared to organic candidate molecules.

   Taking a step further in material design, the presence of porosity coupled with water stability will allow corresponding materials to be utilized in applications beyond therapeutics, from water purification and disinfection, desalination, anti-fouling coatings, personal protective equipment (PPE) antibacterial coatings, antibacterial coatings in respirators, to food packaging applications.  

  Considering the above, we develop multi-functional semiconductor materials of nontoxic composition, with fine-tunable porosity and permanent water stability, which are activated using visible light and exhibit broad spectrum antibacterial activity.

Chiral/Magnetic Semiconductors

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1. A. Azmy, et al., Inorg. Chem. 2023, accepted

   Metal Halide Semiconductors (MHS) feature attributes, such as the presence of large and tunable spin-orbit coupling (SOC), spin-dependent optical selection rules, and tunable Rashba/Dresselhaus (R/D) spin splitting, which render them exceptional candidates for next-generation spin-orbitronic and quantum computing devices.

   Towards this end, our group focuses on the development of non-toxic, environmentally stable MHS, which are utilized as a platform for shedding light on underlying structure-property relationships in terms of R/D spin splitting for efficient spin manipulation.

Funding Support

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